Solvent-free, visible-light photocatalytic alcohol oxidations applying an organic photocatalyst
نویسندگان
چکیده
A method for the solvent-free photocatalytic conversion of solid and liquid substrates was developed, using a novel rod mill apparatus. In this setup, thin liquid films are realized which is crucial for an effective photocatalytic conversion due to the low penetration depth of light in heterogeneous systems. Several benzylic alcohols were oxidized with riboflavin tetraacetate as photocatalyst under blue light irradiation of the reaction mixture. The corresponding carbonyl compounds were obtained in moderate to good yields.
منابع مشابه
Oxidative Photodegradation of Evans Blue Dye Using N-Doped Zinc Oxide
The photocatalytic degradation of Evans Blue has been studied under visible light in the presence of N-doped ZnO as a photocatalyst. N-doped ZnO was prepared by the solvent free method. The photocatalytic activity of ZnO and N-doped ZnO was compared by investigating the photodegradation of Evans Blue dye under visible light. The effect of different parameters like pH, concentration of the Dye, ...
متن کاملContents: (Adv. Sci. 8/2017)
Bye bye palladium. Kai A. I. Zhang and coworkers develope a palladium-free and photocatalytic Stille-type coupling reaction of aryl iodides and aryl stannanes by a conjugated micro porous polymer-based photocatalyst under visible light irradiation at room temperature in article number 1700101. Via the aryl radical-mediated reaction pathway, the light-promoted coupling reaction using a pure orga...
متن کاملForming heterojunction: an effective strategy to enhance the photocatalytic efficiency of a new metal-free organic photocatalyst for water splitting
Photocatalytic water splitting is a new technology for the conversion and utilization of solar energy and has a potential prospect. One important aspect of enhancing the photocatalytic efficiency is how to improve the electron-hole separation. Up to now, there is still no ideal strategy to improve the electron-hole separation. In this article, for metal-free organic photocatalysts, we propose a...
متن کاملVisible-light-driven photooxidation of alcohols using surface-doped graphitic carbon nitride
In recent years, graphitic carbon nitride (g-C3N4) has received substantial interest as a photocatalyst for metal-free, visiblelight promoted reactions. It exhibits a graphite-like, layered structure wherein tris-triazine units are connected through C–N-bonds forming a two-dimensional layer. g-C3N4 can be synthesized via various methods such as pyrolysis of urea or other nitrogen-rich precursor...
متن کاملNear-infrared light controlled photocatalytic activity of carbon quantum dots for highly selective oxidation reaction.
Selective oxidation of alcohols is a fundamental and significant transformation for the large-scale production of fine chemicals, UV and visible light driven photocatalytic systems for alcohol oxidation have been developed, however, the long wavelength near infrared (NIR) and infrared (IR) light have not yet fully utilized by the present photocatalytic systems. Herein, we reported carbon quantu...
متن کامل